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Beilstein J. Org. Chem. 2024, 20, 427–435, doi:10.3762/bjoc.20.37
Graphical Abstract
Figure 1: Structure of fluoranthene.
Scheme 1: Pd-catalyzed access to fluoranthenes.
Scheme 2: Scope of the Pd-catalyzed direct arylation reaction of arenes with 1,8-dibromonaphthalene.
Scheme 3: Scope of the Pd-catalyzed direct arylation reaction of 2,5-substituted heteroarenes with 1,8-dibrom...
Scheme 4: Scope of the Pd-catalyzed Suzuki reaction followed by direct arylation of arylboronic acids with 1,...
Scheme 5: Attempted reaction of 1-naphthylboronic acid with 1,2-dihalobenzenes.
Scheme 6: Pd-catalyzed Heck reaction followed by direct arylation of 1,1-diphenylethylene with 1,2-dihalobenz...
Beilstein J. Org. Chem. 2017, 13, 2862–2868, doi:10.3762/bjoc.13.278
Scheme 1: Reported Pd-catalyzed heteroarylations of bromoselenophenes.
Scheme 2: Palladium-catalyzed heteroarylations of 2-bromoselenophene. *: 110 °C
Scheme 3: Palladium-catalyzed 2,5-diheteroarylation of 2,5-dibromoselenophene.
Scheme 4: Synthesis of 2-aryl-5-(heteroaryl)selenophenes.
Scheme 5: Proposed catalytic cycle.